STANLEY I.SANDLER earned the B．Ch．E．degree in 1962 from the City College of New Y0rk．a(chǎn)nd the Ph．D．in chemical engineering from the University of Minnesota in 1966．He was then a National Science Foundation Postdoctoral Fellow at the Institute for Molecular Physics at the University of Maryland for the 1966-67 academic year．He joined the faculty of the University of Delaware in 1967 as all assistant professor，and was promoted to associate professor in 1970．professor in 1973 and Henry Belin du Pont Professor of Chemical Engineering in 1982．He was department chairman from 1 982 to 1986．He currently is also professor of chemistry and biochemistry at the University of Delaware and founding director of its Center for Molecular and Engineering Thermodynamics．He has been a visiting professor at Imperial College（London），the Technical University of Berlin．the University of Queensland（Australia）and the University of California．Berkeley．In addition to this book．Professor Sandier is the author of 225 research papers and a monograph，and he is the editor of a book on thermodynamic modeling and five conference proceedings．Among his many awards and honors are a Faculty Scholar Award（1971）from the Camille and Henry Dreyfus Foundation，a Research Fellow-ship（1980）and US．Senior Scientist Award（1988）from the Alexander von Humboldt Foundation（Germany），the 3M Chemical Engineering Lectureship Award （1988）from the American Society for Engineering Education，the Professional Progress（1984）and Warren K．Lewis Awards（1996）from the American Institute of Chemical Engineers，the E．V Murphree Award（1996）from the American Chemical Society， the Rossini Lectureship Award（1 997）from the International Union of Pure and Applied Chemistry， and election to the US．National Academy of Engineering
圖書目錄
NOTATION CHAPTENR 1 INTRODUCTION 1.1 the Central Problems of Thermodynamics 11.2 A System of Units 31.3 The Equilibrium State 51.4 Pressure , Temperature , and Equilibrium 71.5 Heat , Work , and the Conservation of Energy 121.6 Specification of the Equilibrium State ; Intensive and Extensive Variables; Equations of State 151.7 A Summary of Important Experimental Observations 181.8 A Comment on the Development of Thermodynamics 20 CHAPTER 2 CONSERVATION OF MASS AND ENERGY 22 2.1 A General Balance Equation and Conserved Quantities 23 2.2 Conservation of Mass 272.3 Conservation of Energy 302.4 The Thermodynamic Properties of Matter 432.5 Applications of the Mass and Energy Balances 512.6 Conservation of Momentum 752.7 The Microscopic Equations of Change for Thermodynamics and Fluid Mechanics (Optional) 76 CHAPTER 3 ENTROPY: AN ADDITIONAL BALANCE EQUATION 893.1 Entropy: A New Concept 903.2 The Entropy Balance and Reversibility 973.3 Heat, Work , Engines, and Entropy 1033.4 Entropy Changes of Matter 1123.5 Applications of the Entropy Balance 1153.6 Liquefaction 1283.7 Power Generation and Refrigeration Cycles 1323.8 The Thermodynamics of Mechanical Explosions 1543.9 The Microscopic Entropy Balance (Optional) 163 CHAPTER 4 THE THERMODYNAMIC PROPERTIES OF REAL SUBSTANCES 1754.1 Some Mathematical Preliminaries 1754.2 The Evaluation of Thermodynamic partial Derivatives 1794.3 The Ideal Gas and Absolute-Temperature Scales 1944.4 The Evaluation of Change in the Thermodynamic Properties of Real Substances Accompanying a Change of State 1954.5 An Example Involving the Change of State of a Real Gas 2194.6 The Principle of Corresponding States 2254.7 Generalized Equations of State 2384.8 The Third Law of Thermodynamics 2424.9 More About Thermodynamic Partial Derivatives (Optional ) 243 CHAPTER 5 EQUILIBRIUM AND STABILITY IN ONE- COMPONENT SYSTEMS 2605.1 The Criteria for Equilibrium 2605.2 Stability of Thermodynamic Systems 2655.3 Phase Euqilibria : Application of the Equilibrium and Stability 2725.4 The Molar Gibbs Free Energy and Fugacity of a Pure Component 2795.5 The Calculation of Pure Fluid-Phase Equilibrium: The Computation of Vapor Pressure from an Equilibrium of State 2955.6 The Specification of the Equilibrium Thermodynamic State of a System of Several Phases : The Gibbs Phase Rule for a One-Component System 3035.7 Thermodynamic Properties of Phase Transitions 307 CHAPTER 6 THE THERMODYNAMICS OF MULTICOMPONENT MIXTURES 3246.1 The Thermodynamic Description of Mixtures 3246.2 The Partial Molar Gibbs Free Energy and the Generalized Gibbs-Duhem Equation 3336.3 A Notation for Chemical Reactions 3376.4 The Equations of Change for a Multicomponent System 3406.5 The Heat of Reaction and a Convention for the Thermodynamic Properties of Reacting Mixtures 3496.6 The Experimental Determination of the Partial Molar Volume and Enthalpy 3546.7 Criteria for Phase Equilibrium in Multicomponent Systems 3646.8 The Criteria for Chemical Equilibrium, and Combined Chemical and Phase Equilibrium 3686.9 The Specifica
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