Preface Chapter 1 THERMODYNAMICS 1.1 Physical Chemistry 1.2 Thermodynamics 1.3 Temperature 1.4 The Mole 1.5 Ideal Gases 1.6 Differential Calculus 1.7 Equations of State 1.8 Integral Calculus 1.9 Study Suggestions 1.10 Summary Chapter 2 THE FIRST LAW OF THERMODYNAMICS 2.1 Classical Mechanics 2.2 P-V Work 2.3 Heat 2.4 The First Law of Thermodynamics 2.5 Enthalpy 2.6 Heat Capacities 2.7 The Joule and Joule-Thomson Experiments 2.8 Perfect Gases and the First Law 2.9 Calculation of First-Law Quantities 2.10 State Functions and Line Integrals 2.11 The Molecular Nature of Internal Energy 2.12 Problem Solving 2.13 Summary Chapter 3 THE SECOND LAW OF THERMODYNAMICS 3.1 The Second Law of Thermodynamics 3.2 Heat Engines 3.3 Entropy 3.4 Calculation of Entropy Changes 3.5 Entropy, Reversibility, and Irreversibility 3.6 The Thermodynamic Temperature Scale 3.7 What Is Entropy？ 3.8 Entropy, Time, and Cosmology 3.9 Summary Chapter 4 MATERIAL EQUILIBRIUM 4.1 Material Equilibrium 4.2 Entropy and Equilibrium 4.3 The Gibbs and Helmholtz Energies 4.4 Thermodynamic Relations for a System in Equilibrium 4.5 Calculation of Changes in State Functions 4.6 Chemical Potentials and Material Equilibrium 4.7 Phase Equilibrium 4.8 Reaction Equilibrium 4.9 Entropy and Life 4.10 Summary Chapter 5 STANDARD THERMODYNAMIC FUNCTIONS OF REACTION 5.1 Standard States of Pure Substances 5.2 Standard Enthalpy of Reaction 5.3 Standard Enthalpy of Formation 5.4 Determination of Standard Enthalpies of Formation and Reaction 5.5 Temperature Dependence of Reaction Heats 5.6 Use of a Spreadsheet to Obtain a Polynomial Fit 5.7 Conventional Entropies and the Third Law 5.8 Standard Gibbs Energy of Reaction 5.9 Thermodynamics Tables 5.10 Estimation of Thermodynamic Properties 5.11 The Unattainability of Absolute Zero 5.12 Summary Chapter 6 REACTION EQUILIBRIUM IN IDEAL GAS MIXTURES 6.1 Chemical Potentials in an Ideal Gas Mixture 6.2 Ideal-Gas Reaction Equilibrium 6.3 Temperature Dependence of the Equilibrium Constant 6.4 Ideal-Gas Equilibrium Calculations 6.5 Simultaneous Equilibria 6.6 Shifts in Ideal-Gas Reaction Equilibria 6.7 Summary Chapter 7 ONE-COMPONENT PHASE EQUILIBRIUM AND SURFACES 7.1 The Phase Rule 7.2 One-Component Phase Equilibrium 7.3 The Clapeyron Equation 7.4 Solid-Solid Phase Transitions. …… Chapter 8 REAL GASES Chapter 9 SOLUTIONS Chapter 10 NONIDEAL SOLUTIONS Chapter 11 REACTION EQUILIBRIUM IN NONIDEAL SYSTEMS Chapter 12 MULTICOMPONENT PHASE EQUILIBRIUM Chapter 13 ELECTROCHEMICAL SYSTEMS Chapter 14 KINFTIC THEORY OF GASES Chapter 15 TRANSPORT PROCESSES Chapter 16 REACTION KINETICS Chapter 17 QUANTUM MECHANICS Chapter 18 ATOMIC STRUCTURE Chapter 19 MOLECULAR ELECTRONIC STRUCTURE Chapter 20 SPECTROSCOPY AND PHOTOCHEMISTRY Chapter 21 STATISTICAL MECHANICS Chapter 22 THEORIES OF REACTION RATES Chapter 23 SOLIDS AND LIQUIDS Bibliography Appendix Answers to Selected Problems Index
鄂公網(wǎng)安備 42010302001612號(hào) 