Metal-Promoted Organic Reactions

1 Heterocycle Synthesis through Direct Coupling of Aromatic and Vinylic C-H Bonds
1.1 Introduction
1.2 Construction of carbazoles
1.2.1 Tandem C H functionalization and C N bond formation
1.2.2 Pd （OAc）2 catalyzed oxidative biaryl synthesis
1.3 Construction of benzoxazoles
1.4 Construction of benzimidazoles
1.5 Construction of 2 substituted benzothiazoles
1.6 Construction of 3 aryl/alkylindazoles
1.7 Construction of indoles
1.8 Construction of indole derivatives oxindoles and indolines
1.8.1 Construction of oxindoles
1.8.2 Construction of indolines
1.9 Construction of benzolactams and phthalimides
1.10 Construction of dibenzofurans
1.11 Construction of brigehead unsaturated bicyclic enamines
1.12 Conclusion
References

2 Heterocycle Synthesis through Direct Coupling of Saturated C-H Bonds
2.1 Introduction
2.2 Intramolecular cyclization
2.2.1 C C bond formation
2.2.2 C N bond formation
2.2.3 C O bond formation
2.3 Intermolecular cyclization
2.3.1 Cyclization with insertion of alkenes
2.3.2 Cyclization with insertion of CO
2.3.3 Cyclization with insertion of alkynes
2.4 Conclusions
References

3 Direct Coupling of Aromatic C-H Bonds with a Nitrogen Atom
3.1 Introduction
3.2 C N bond formation of arenes having directing groups
3.2.1 Copper catalyzed/mediated C N bond formation
3.2.2 Palladium catalyzed C N bond formation
3.3 Copper（Ⅱ） acetate catalyzed/mediated C N bond formation of polyfluoro（chloro）arenes
3.4 Metal free C N bond formation of alkyl substituted arenes
3.5 Conclusion

References
4 Direct Coupling of Azole C-H Bonds with Nitrogen Groups
4.1 Introduction
4.2 Copper catalyzed/mediated amination
4.3 Acid promoted amination
4.4 Metal free amination
4.5 Conclusion
References

5 Copper-Promoted Direct sp2C-H Bond Transformation
5.1 Introduction
5.2 Aromatic ring C H bond functionalization
5.2.1 Cyclization C H bond functionalization
5.2.2 Non cyclization C H bond functionalization
5.3 Heteroaromatic C H bond functionalization
5.3.1 Arylation of heteroaromatic C H bonds
5.3.2 Alkenylation of oxazoles with bromoalkenes
5.3.3 Amination of heteroaromatic C H bonds
5.4 Conclusion
References

6 lron Catalysis for Hydrosilyaltion
6.1 Introduction
6.2 Hydrosilylation of olefins
6.3 Hydrosilylation of aldehydes and ketones
6.4 Hydrosilylation reduction of amides to amines
6.5 Conclusion
References

7 Stereoselective Formation Chiral Heterocyclic Compounds via Cross Dehydrogenative Coupling Reactions of sp3C-H Bonds
7.1 Introduction
7.2 Copper catalyzed synthesis of tetrahydroisoquinoline derivatives
7.3 Organocatalytic synthesis of xanthene and indole derivatives
7.4 Copper catalyzed synthesis of indole derivatives
7.5 Conclusion
References

8 Synthesis of Cyclpentadienyl Titanium or Zirconium Complexes and Application in Hydrogenation of Olefins
8.1 Synthesis of cyclopentadienyl zirconium complexes
8.2 Synthesis of cyclopentadienyl titanium complexes
8.3 Hydrogenation of olefins using titanocenes
References